AVS 66th International Symposium & Exhibition
    Plasma Science and Technology Division Tuesday Sessions
       Session PS+EM-TuA

Invited Paper PS+EM-TuA10
Meeting the Challenges in Patterning Phase Change Material for Next Generation Memory Devices

Tuesday, October 22, 2019, 5:20 pm, Room B131

Session: Advanced BEOL/Interconnect Etching and Advanced Memory and Patterning
Presenter: Meihua Shen, Lam Research Corporation
Authors: M. Shen, Lam Research Corporation
L. Thorsten, Lam Research Corporation
J. Hoang, Lam Research Corporation
S. Chiou, Lam Research Corporation
D. Qian, Lam Research Corporation
A. Routzahn, Lam Research Corporation
J.K. Chen, Lam Research Corporation
A. Dulkin, Lam Research Corporation
J. Sims, Lam Research Corporation
A. McKerrow, Lam Research Corporation
R. Dylewicz, Lam Research Corporation
Correspondent: Click to Email

Phase change materials (PCM) have emerged as the leading candidate for next generation non-volatile memory device with unique characteristics that significant differ from conventional DRAM and NAND flash memory. Recently, 3-D Cross point PCRAM, for example, has transitioned into high volume production, demonstrating a non-volatile memory product exhibiting faster speed, low voltage operation and high density.

Phase change materials are typically chalcogenide alloys containing elements such as Ge, Sb, Se, Te with various dopants. The materials exhibited phase change between amorphous insulating state and the crystalline conductive state under thermal/electric heating. To ensure electric device performance, it is critically important to maintaining the PCM elemental composition and structure integrity during patterning. The challenges of patterning PCM come from the soft nature of the material and the damages that can easily occur during plasma dry etch, ambient air exposure, wet clean and encapsulation process. To meet the challenges, we developed an integrated system combining dry etch, wet clean and ALD encapsulation modules together. In this paper, we will present the comprehensive studies on each module as well as the interactions of the modules in successful patterning of the phase change materials. The discussions will be focused key learnings on how to maintain the feature fidelity and the integrity of the materials during etch and encapsulation.