AVS 66th International Symposium & Exhibition | |
Atomic Scale Processing Focus Topic | Tuesday Sessions |
Session AP+EL+MS+PS+SS+TF-TuA |
Session: | Advancing Metrology and Characterization to enable Atomic Layer Processing |
Presenter: | Riikka Puurunen, Aalto University, Finland |
Correspondent: | Click to Email |
Conformal thin films which cover complex 3D shapes with a film of uniform properties (thickness, composition, etc.) are increasingly demanded applications such as semiconductor devices, microelectromechanical systems, energy conversion/storage and catalysis. Atomic layer deposition (ALD) and its counterpart atomic layer etching (ALE) [together known as atomic layer processing (ALP)], are increasing in usage largely thanks to their known conformal character.
A question that needs to be asked in the R&D of 3D applications using conformal ALD/ALE processes is: how conformal is conformal; is the conformality sufficient to meet the specs? In semicon industry, vertical vias and cross-sectional transmission electron microscopy (TEM) are standardly used for conformality analysis. Recently, microscopic lateral high-aspect-ratio (LHAR) test structures have been developed to improve the conformality analytics capabilities. LHAR structures e.g. enable detailed conformality analysis at arbitrarily high aspect ratios (e.g., >5000:1), where no film can coat the 3D structure fully, thereby exposing the saturation profile characteristic for the process. This, in turn enables the kinetic analysis of the process and e.g. extraction of the sticking coefficients related to the growth reactions.
This invited talk will address recent progress related to the fabrication and the use of microscopic LHAR conformality test structures. After the breakthrough with the first prototypes (PillarHall LHAR1; Gao et al. 2015, Mattinen et al. 2016; reviewed in Cremers et al., 2019), third and fourth generation prototypes have been developed (PillarHall LHAR3 and LHAR4). This work will review the conformality analysis progress enabled by the microscopic LHAR structures and discuss the benefits and challenges of this approach. Recent published progress includes the conformality modelling by Ylilammi et al. (2018) and experimental extraction of sticking coefficient by Arts et al. (2019). In addition, several other ongoing conformality analysis cases will be presented.
References
Arts, Vandalon, Puurunen, Utriainen, Gao, Kessels, Knoops, J. Vac. Sci. Technol. A 37, 030908 (2019); https://doi.org/10.1116/1.5093620
Cremers, Puurunen, Dendooven, Appl. Phys. Rev. 6, 021302 (2019); https://doi.org/10.1063/1.5060967
Gao, Arpiainen, Puurunen, J. Vac. Sci. Technol. A 33, 010601 (2015); https://doi.org/10.1116/1.4903941
Mattinen, Hämäläinen, Gao, Jalkanen, Mizohata, Räisänen, Puurunen, Ritala, Leskelä, Langmuir, 32, 10559 (2016); http://doi.org/10.1021/acs.langmuir.6b03007
Ylilammi, Ylivaara, Puurunen, J. Appl. Phys. 123, 205301 (2018); https://doi.org/10.1063/1.5028178