AVS 65th International Symposium & Exhibition | |
Plasma Science and Technology Division | Tuesday Sessions |
Session PS-TuP |
Session: | Plasma Science and Technology Division Poster Session |
Presenter: | Ting-Ting Pan, National Taiwan University, Taiwan, Republic of China |
Authors: | T.-T. Pan, National Taiwan University, Taiwan, Republic of China S.-Y. Lin, National Taiwan University, Taiwan, Republic of China C.-C. Hsu, National Taiwan University, Taiwan, Republic of China |
Correspondent: | Click to Email |
In this work, we develop a system that contains a plasma generation device, a piezoelectric spray, and a spectrometer to detect metallic ions in solution. The plasma consists of a needle and a copper sheet as the anode and the cathode respectively. This plasma is driven by a homemade high voltage module that delivers 3 kV DC and is powered by a 5 V commercial portable power bank. The plasma is ignited in ambient air without the need of any purging gases. The mist of metal-ion-containing solution is sprayed to the plasma. The optical emission of the plasma is analyzed using a spectrometer for metallic element analysis. Such an arrangement allows for analysis of solutions with a wide range of electrical conductivities.
It is shown that the addition of a ballast resistor in series of the high voltage module effectively limits the current and plays an important role for metal detection. Without the ballast resistor, no metallic emission line is observed, despite of the fact that the plasma shows very bright emission. With the use of a ballast resistor of proper resistance, plasma appears to be more stable and clear Na and Pb emission lines are observed when a solution containing 1000 and 10000 ppm of Na and Pb, respectively, is spray to the plasma. We also observe that the gap between the electrodes is very critical for plasma characteristics. With a gap smaller than 0.5 mm, the plasma exhibits stable (DC) IV waveforms, while it shows self-pulsing characteristics with a gap greater than 0.5 mm.
We will show the progress toward the ultimate goal of this work: development of a system to detect metal ions in solution by integrating the plasma and spray devices with a home-made low cost spectrometer, and control the system using a Raspberry pi, a portable computer. Such an integrated system is fully functionalized and standalone and allows for simultaneous detection of multiple metal ions using plasma spectroscopy.