AVS 65th International Symposium & Exhibition
    Plasma Science and Technology Division Tuesday Sessions
       Session PS-TuP

Paper PS-TuP6
Aspect-ratio and Line-edge Fluctuation Controlled Nanolithography using Poly(styrene-b-Dimethylsiloxane) and Amorphous Carbon Layer

Tuesday, October 23, 2018, 6:30 pm, Room Hall B

Session: Plasma Science and Technology Division Poster Session
Presenter: JiSoo Oh, Sungkyunkwan University, Republic of Korea
Authors: J.S. Oh, Sungkyunkwan University, Republic of Korea
G.Y. Yeom, Sungkyunkwan University, Republic of Korea
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Of the various alternative lithography technologies, direct self-assembly (DSA) patterning technology using block copolymer (BCP) has received great attention due to excellent pattern resolution, process simplicity, low cost, and long-range ordering (good scalability).

Polystyrene-block-polydimethylsiloxane (PS-b-PDMS) with high Flory-Huggins interaction parameter (χ) have been extensively studied because they provide ultra-fine patterning and improved pattern quality. However, due to the preferential segregating property of PDMS in air and PS interface, it is disadvantageous to vertical orientation and it is difficult to fabricate BCP patterns with high aspect ratio (HAR)

Here, we will introduce the process of effectively pattern transfer by inserting an amorphous carbon layer (ACL) between the PS-b-PDMS BCP patterns and the underlying silicon substrate. In this study, we have overcome limitations of PS-b-PDMS BCP patterns with low aspect ratios by developing an etch selectivity close to infinity using plasma etch process. The PDMS patterns of various shapes could be fabricated into lamellar, rod, hole pattern with HAR by pattern transfer to ACL due to high etch selectivity plasma process. Also, line edge roughness (LER) and line width roughness (LWR) was improved due to the plasma trimming effect.