AVS 65th International Symposium & Exhibition
    Plasma Science and Technology Division Tuesday Sessions
       Session PS-TuP

Paper PS-TuP11
Etch Characteristics of Nanometer-scale Patterned Cu Thin Film Using Pulse- modulated RF Source Plasma

Tuesday, October 23, 2018, 6:30 pm, Room Hall B

Session: Plasma Science and Technology Division Poster Session
Presenter: Euntaek Lim, INHA University, Republic of Korea
Authors: E.T. Lim, INHA University, Republic of Korea
J.S. Ryu, INHA University, Republic of Korea
C.W. Chung, INHA University, Republic of Korea
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The critical dimensions of the semiconductor devices have been shrunk for better performance and functionality. As the minimum feature length keeps decreasing, the aluminum metal electrodes and wiring can not be used anymore and the need to use copper wiring instead of aluminum is increasing. Copper has very low resistance and high electromigration resistance, so the copper thin films is known as an excellent interconnect material compared to aluminum although the copper is more expensive than aluminum. In order to apply copper films into the interconnect, the pattering and etching process of copper films should be developed. Up to date, the studies on etch characteristics of copper thin films were performed using Cl2, HBr, and H2 gases but the satisfactory results were not obtained.

In this study, the pulse-modulated RF plasma etching of copper thin films has been introduced to achieve good etch results such as proper etch rate and good etch profile compared to those by the conventional continuous wave (CW) plasma etching which can produce low etch selectivity, etch residues, and poor etch profiles. This modulated plasma can provide the specific plasma conditions modified by special matching system that can change on-off duty ratio of 13.56 MHz RF power and frequency on the specific duty ratio. Currently, no good etch gases have been known to etch copper thin films. In this research, etching characteristics of copper thin film masked with nanometer-scale patterns was investigated in carboxylic acid using pulse-modulated inductively coupled plasma reactive ion etching (ICP RIE). The effects of on-off duty ratio and frequency of pulsed plasma on the etch characteristics of copper were examined.

Acknowldgments This research was supported by the MOTIE(Ministry of Trade, Industry & Energy (10080450) and KSRC(Korea Semiconductor Research Consortium) support program for the development of the future semiconductor device.