AVS 65th International Symposium & Exhibition
    Plasma Science and Technology Division Monday Sessions
       Session PS+TF-MoM

Paper PS+TF-MoM11
The Effects of Varying Plasma Conditions on Plasma Enhanced Atomic Layer Epitaxy

Monday, October 22, 2018, 11:40 am, Room 104C

Session: Plasma Deposition and Plasma-Enhanced ALD
Presenter: Charles R. Eddy, Jr., U. S. Naval Research Laboratory
Authors: D.R. Boris, U.S. Naval Research Laboratory
V.D. Wheeler, U.S. Naval Research Laboratory
V.R. Anderson, Kennesaw State University
N. Nepal, U.S. Naval Research Laboratory
S.G. Rosenberg, ASEE Postdoctoral Fellow
A.C. Kozen, ASEE Postdoctoral Fellow
S.G. Walton, U.S. Naval Research Laboratory
C.R. Eddy, Jr., U. S. Naval Research Laboratory
Correspondent: Click to Email

Plasma enhanced atomic layer epitaxy (PEALE) is a method for growing very thin crystalline films at low temperature in a conformal layer-by-layer manner that is based on a pair of self-terminating and self-limiting gas-surface half-reactions, in which at least one half-reaction involves species from a plasma. This approach generally offers the benefit of substantially reduced growth temperatures and greater flexibility in tailoring the gas phase chemistry to produce varying film characteristics. The flexibility and lower growth temperatures that plasmas provide come at the cost of a complex array of process variables that often require great care on the part of the user.

In response to this challenge, this work focuses on the use of plasma diagnostics to inform the choice of process conditions for PEALE systems. In this work we employ VUV-NIR spectroscopy and charged particle collectors to characterize the inductively coupled plasma source of a Fiji 200 (Ultratech/CNT) ALD tool. In particular, we assess the total ion flux reaching the substrate surface and the relative fractions of atomic and molecular species generated in the plasma under a variety of pressures and gas input flow fractions in context of PEALE of AlN, InN, TiO2 and Ga2O3 films. Changes in plasma parameters are then linked with changes in film characteristics.

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* This work supported by the Naval Research Laboratory Base Program