AVS 65th International Symposium & Exhibition
    Spectroscopic Ellipsometry Focus Topic Monday Sessions
       Session EL+EM-MoA

Paper EL+EM-MoA9
Use of Ellipsometry to Monitor Implant Damage in Methane Plasma Implant

Monday, October 22, 2018, 4:00 pm, Room 202A

Session: Spectroscopic Ellipsometry: Novel Applications and Theoretical Approaches
Presenter: Nicholas Bateman, Varian Semiconductor Equipment, Applied Materials
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The Applied Materials PLAD tool consists of an inductively couple plasma source and a pulsed direct current (DC) bias coupled to a platen upon which a wafer is e-chucked. This tool architecture enables high throughput for high dose implants. Unlike a standard beamline implant, which will not lead to any deposition on the wafer, the plasma implant process directly exposes the wafer to the plasma leading to both deposition and implant damage. Standard industrial metrologies like Thermawave [1] are sensitive only to the implant damage. Process control could be enhanced if both the implant damage and the deposition thickness could be monitored online.

Ellipsometry is extensively used in the semiconductor industry to measure and monitor film thickness and optical properties [2]. It would be the ideal industrial technique to measure the deposition left by a plasma implant process, but has not been used to evaluate the damage caused by ion implant.

This work presents the development of an ellipsometry model that can be used to simultaneously monitor the deposited layer thickness and the implant damage caused by a methane plasma implant. The dispersion function for the deposited layer was determined by fitting multi-angle, broad wavelength ellipsometry data for different process times and bias conditions. The extracted thickness of the damage layer is shown to be well correlated to Thermawave across a wide range of process parameters, and through an extended ‘marathon’ test. As the implant voltage is reduced to zero the model trends continuously to match the results of a ‘deposition only’ ellipsometry model that matches SEM thickness measurements.

These results suggest that for plasma doping applications, ellipsometry can be used to monitor both implant damage and deposition simultaneously to allow improved process control.

References:

[1] J Opsal, US Patent 5,074,669, Method and apparatus for evaluating ion implant dosage levels in semiconductors (1989)

[2] DE Aspnes, Journal of Vacuum Science & Technology A, 31, 058502 (2013)