AVS 65th International Symposium & Exhibition
    Spectroscopic Ellipsometry Focus Topic Monday Sessions
       Session EL+AS+EM-MoM

Paper EL+AS+EM-MoM10
a-Si as a Protective Layer to Block the Oxidization of Al mirrors

Monday, October 22, 2018, 11:20 am, Room 202A

Session: Application of SE for the Characterization of Thin Films and Nanostructures
Presenter: Yhoshua Wug, University of California at Los Angeles
Authors: Y. Wug, University of California at Los Angeles
D.D. Allred, Brigham Young University
R.S. Turley, Brigham Young University
Correspondent: Click to Email

Arguably, the best path to produce a truly broadband, e.g., an IR-optical-UV-EUV (extreme ultraviolet) mirror, for a future space observatory is an EUV multilayer mirror coated by a very thin bare aluminum layer. However, using a bare Al layer presents challenges that first must be overcome. Al oxidizes rapidly when contact with the atmosphere occurs. The customary solution is to cover the mirror with a protective evaporated fluoride layer. Unfortunately, these are opaque under ~110 nm, whereas, bare Al itself is highly reflective down to 85nm and could be used as a mirror to that wavelength if a barrier were not required. Once the mirror is in space far from the Earth, where there is no oxygen, Al would no longer need a barrier layer. Could a barrier be removed in space? Neither fluorides nor aluminum oxide can be removed once they are deposited without damaging the mirror’s surface and destroying VUV reflectance. a-Si could be used as a protective layer that is potentially removable without roughening the Al surface. Dry hydrogen etching processes exist that could remove a silicon barrier as silane gas which would dissipate quickly in space. Such a process would use the Al layer as an etch stopping barrier in removing the a-Si protective layer. But is a-Si a suitable barrier for Al? We report our variable-angle spectroscopic ellipsometry studies of evaporated a-Si thin films on evaporated Al films. We discuss the conditions where a-Si can act as a protective layer to block aluminum oxidation.