AVS 59th Annual International Symposium and Exhibition
    Plasma Science and Technology Wednesday Sessions
       Session PS2-WeA

Paper PS2-WeA11
Plasma-Surface Interactions, Erosion, and Impact on Plasma Distribution Functions

Wednesday, October 31, 2012, 5:20 pm, Room 25

Session: Plasma Surface Interactions during PECVD and Plasma Surface Modification
Presenter: N. Fox-Lyon, University of Maryland, College Park
Authors: N. Fox-Lyon, University of Maryland, College Park
D.B. Graves, University of California Berkeley
S.Y. Moon, University of Houston
V.M. Donnelly, University of Houston
D.J. Economou, University of Houston
G.S. Oehrlein, University of Maryland, College Park
Correspondent: Click to Email

Plasma-surface interactions can play a large role in changing characteristic plasma distribution functions. To improve our fundamental understanding of these effects, we leverage several plasma characterization techniques (Langmuir probe, ion energy/mass analyzer, optical emission spectroscopy) with real-time characterization by in situ ellipsometry of the eroding plasma-facing surface. Using these methods, we qualitatively and quantitatively studied the time evolution of gaseous and surface derived plasma impurities. High-density inert plasmas (Ar) and low-density reactive plasmas (H2, D2) respond differently to molecular impurities in the plasma. When H2/D2 or surface/gaseous derived CHX -related impurities are introduced into Ar plasma, large changes in plasma properties are observed. We report on changes to the ion energy/mass distributions, electron temperature/distribution functions, and plasma density for different conditions . CHX effects on H2 and D2 plasmas, and H2/D2 plasma mixtures were also investigated. We also explore the effects of changing the relative C:H fluxes into the plasma from eroding surfaces using graphitic (high C:H ratio) and polymeric (lower C:H ratio) films. In steady-state contact with plasmas, hydrocarbons are eroded as C, H, and CHX impurities into the plasma reflective of their initial C:H ratios. Along with these studies, we have compared how varying the gap distance between the plasma generation coil and hydrocarbon substrate electrode affects impurity fluxes and plasma properties. A comparison of plasma properties for two different inductively coupled plasma reactors has also been completed and sheds light on how plasma properties and observed trends change for different geometries and plasma sources.