AVS 65th International Symposium & Exhibition
    Electronic Materials and Photonics Division Wednesday Sessions
       Session EM+2D+SS-WeA

Paper EM+2D+SS-WeA10
Cesium-Free III-Nitride Photocathodes Based on Control of Polarization Charge

Wednesday, October 24, 2018, 5:20 pm, Room 101A

Session: Wide and Ultra-Wide Bandgap Materials for Electronic Devices: Growth, Modeling and Properties
Presenter: Douglas Bell, Jet Propulsion Laboratory, California Institute of Technology
Authors: L.D. Bell, Jet Propulsion Laboratory, California Institute of Technology
E. Rocco, SUNY Polytechnic Institute
F. Shahedipour-Sandvik, SUNY Polytechnic Institute
S. Nikzad, Jet Propulsion Laboratory, California Institute of Technology
Correspondent: Click to Email

III-nitride photocathodes are well-suited for ultraviolet (UV) detection, with commercial, defense, and astronomical applications. Photocathodes detect light by absorbing photons which create electron-hole pairs, and emitting those electrons into vacuum, where they are detected and amplified by a gain-producing device such as a microchannel plate. This type of device is capable of ultra-low dark current and enables photon counting. The wide bandgaps available in the AlGaN family provide intrinsic solar blindness, and the long-wavelength cutoff may be tuned by control of composition.

Among other properties, negative electron affinity (NEA) is desirable for these structures in order to maximize quantum efficiency (QE), or the number of electrons emitted per incident photon. Normally surface cesiation is used to create low or negative electron affinity of the GaN photocathode surface; however, the resulting highly reactive surface must be protected from air during fabrication and use, necessitating a sealed-tube configuration. Even so, the reactive surfaces of these devices cause degraded performance over time. Cesium-free photocathodes would offer lower cost, smaller size and mass, improved robustness, and greater chemical stability, in addition to the major advantages of higher QE and longer lifetimes.

We will report on the use of polarization engineering in order to achieve high QE without the use of Cs. We will discuss progress in design, fabrication, and characterization of polarization-engineered III-nitride photocathodes. An important component of these designs is the use of N-polar GaN and AlGaN. The nitride polarity affects the interface and surface polarization charge, and the ability to achieve low electron affinity depends critically on control of this charge. Designs using polarization charge engineering also enable optimization of the near-surface potential to further increase QE. We will describe the growth challenges of N-polar GaN and AlGaN and its implementation in photocathode devices. We will present results demonstrating high (>15%) QE for non-cesiated N-polar GaN photocathodes, with a clear path toward higher efficiency devices.