AVS 62nd International Symposium & Exhibition
    Plasma Science and Technology Wednesday Sessions
       Session PS+2D+SE-WeM

Paper PS+2D+SE-WeM13
Low Temperature Synthesis of AlYB14 by High Power Pulsed Magnetron Sputtering

Wednesday, October 21, 2015, 12:00 pm, Room 210B

Session: Plasma Diagnostics, Sensors and Control II
Presenter: Oliver Hunold, RWTH Aachen University, Germany
Authors: O. Hunold, RWTH Aachen University, Germany
Y.T. Chen, RWTH Aachen University, Germany
D. Music, RWTH Aachen University, Germany
P.O.A. Persson, Linköping University, Sweden
J.M. Schneider, RWTH Aachen University, Germany
Correspondent: Click to Email

The influence of ion bombardment on the structure evolution of AlYB14 was studied by using high power pulsed magnetron sputtering (HPPMS). The structure was analyzed by X-ray and electron diffraction. The diffraction data are consistent with the formation of crystalline AlYB14 domains in an amorphous matrix. As the growth temperature was 675 °C synthesis was conducted at 725 °C below the bulk synthesis temperature. It is reasonable to assume that this decrease in the growth temperature is facilitated by bombardment of ions formed in the HPPMS discharge resulting in enhanced surface diffusion and hence higher adatom mobility. This work may be relevant for synthesizing other boron rich solids with low symmetry crystal structures at temperatures well below their bulk synthesis temperature.