AVS 60th International Symposium and Exhibition
    Thin Film Thursday Sessions
       Session TF-ThP

Paper TF-ThP13
Optical and Structural Properties of GaN Thin Films as Grown by Closed-Space Vapor Transport

Thursday, October 31, 2013, 6:00 pm, Room Hall B

Session: Thin Films Poster Session
Presenter: J. Aguilar-Hernández, ESFM-IPN, Mexico
Authors: L.A. Hernández-Hernández, ESFM-IPN, Mexico
J. Aguilar-Hernández, ESFM-IPN, Mexico
F. De Moure-Flores, ESFM-IPN, Mexico
A. Escamilla-Esquivel, ESFM-IPN, Mexico
M. López-López, CINVESTAV-IPN, Mexico
G. Santana-Rodríguez, IIM-UNAM, Mexico
M. Meléndez-Lira, CINVESTAV-IPN, Mexico
A. Hernández-Hernández, CINVESTAV-IPN, Mexico
J.G. Quiñones-Galván, ININ, Mexico
O. De Melo-Pereira, UH, Cuba
G. Contreras-Puente, ESFM-IPN, Mexico
Correspondent: Click to Email

We report in this work the structural and optical properties of GaN films grown by the Closed-Space Vapor Transport (CSVT) technique. The samples were deposited on quartz substrates using GaN powder as the starting material source, which were contained inside a semi-hermetic cell made of graphite in a low pressure atmosphere. We present the characterization carried out by X-Ray Diffraction (XRD), Scanning Electron Microscopy (SEM), Energy Dispersive Spectroscopy (EDS) and Photoluminescence (PL) measurements. XRD results exhibit the growth of low quality hexagonal GaN, while SEM image shows GaN clusters over the entire substrates surface. Concerning EDS measurements they indicated that non-stoichiometric GaN films with non-intentional carbon (C) impurification were obtained. Finally, PL measurements under UV excitation (He:Cd laser λ=325 nm), present PL emission at room temperature. We observed the presence of different emission bands in the visible region: the yellow (YL) at 2.20 eV and the blue (BL) at 2.7-3.0 eV bands are related to undoped and C-doped GaN, while, the green (GL-2) band at 2.36 eV is related to Ga-rich GaN.

: partially funded by CONACyT-SENER, ICyTDF and DGAPA-UNAM PAPIIT.