AVS 49th International Symposium
    Organic Films and Devices Wednesday Sessions
       Session OF+EL-WeP

Paper OF+EL-WeP11
Controlled Growth of Ultrathin Molecular Films

Wednesday, November 6, 2002, 11:00 am, Room Exhibit Hall B2

Session: Organic Films and Devices
Presenter: E.J. Kintzel, Jr., Florida State University
Authors: E.J. Kintzel, Jr., Florida State University
D.-M. Smilgies, Cornell High Energy Synchrotron Source, Cornell University
J.G. Skofronick, Florida State University
S.A. Safron, Florida State University
D.H. Van Winkle, Florida State University
Correspondent: Click to Email

Controlled growth of the aromatic p-phenylene oligomer molecules adsorbed onto KBr(001), KCl(001), NaCl(001), and NaF(001), has been investigated by x-ray diffraction (XRD) and atomic force microscopy (AFM). XRD analysis provides evidence that the substrate temperature during deposition, substrate lattice constant, and molecular length affects the molecular orientations within these ultrathin films. AFM images contribute independent evidence for a surface microstructure evolution that is consistent with the XRD results. Oriented films can therefore be grown with the desired molecular orientations by careful selection of an appropriate combination of the above deposition parameters.