AVS 45th International Symposium
    Nanometer-scale Science and Technology Division Thursday Sessions
       Session NS-ThM

Paper NS-ThM3
Chemically Assisted Ion-Beam Etching of Submicrometer Features in GaSb-based Quantum Wells

Thursday, November 5, 1998, 9:00 am, Room 321/322/323

Session: Nanoscale Patterning and Modification
Presenter: G. Nagy, Columbia University
Authors: G. Nagy, Columbia University
R.U. Ahmad, Columbia University
M. Levy, Columbia University
R.M. Osgood, Jr., Columbia University
M.J. Manfra, Massachusetts Institute of Technology
G.W. Turner, Massachusetts Institute of Technology
Correspondent: Click to Email

GaSb-based semiconductor systems are of interest because of their potential applications in advanced microelectronic and optical devices. For example, GaSb-based materials have been used for the fabrication of resonant interband tunneling devices, as well as high performance laser diodes, and midinfrared photodetectors. Anisotropic, high-resolution dry etching is a desirable processing technology for device fabrication in this semiconductor system. Here, we have used electron beam patterning and chemically assisted ion beam etching to fabricate structures down to 200 nm in diameter in GaSb and in GaInAsSb/AlGaAsSb multiple quantum well material. The chemically assisted ion beam etching was performed with chlorine as the reactive gas and Ar@super +@ ions of 400-900 eV energy. With the GaSb substrate, the Cr masks used to fabricate the features exhibited good etch selectivity and smooth, highly anisotropic structures were realized. The measured etch rates of GaSb were successfully fitted to a model of chlorine-based chemically assisted ion beam etching that assumes the formation and desorption of trichloride etch product species. With the GaInAsSb/AlGaAsSb multiple quantum well material, the chemically assisted ion beam etching provided highly anisotropic pattern transfer using Cr as the mask material. Efforts are underway to examine the dependence of etch damage on incident ion energy for 200-1000 nm diameter features in the multiple quantum well material using photoluminescence spectroscopy at 4K.