Pacific Rim Symposium on Surfaces, Coatings and Interfaces (PacSurf 2018)
    Thin Films Monday Sessions
       Session TF-MoE

Paper TF-MoE2
Rheology Behavior and Flash Light Sintering Characteristics of Cu/Ag hybrid-ink for Multi-layered Flexible Printed Circuit Board (FPCB) Application in Printed Electronics

Monday, December 3, 2018, 6:00 pm, Room Naupaka Salons 4

Session: Nanostructured Surfaces and Thin Films: Synthesis and Characterization II
Presenter: Ji-Hyeon Chu, Hanyang University, Seoul, Korea
Authors: J.H. Chu, Hanyang University, Seoul, Korea
S.J. Joo, Hanyang University, Seoul, Korea
H.-S. Kim, Hanyang University, Seoul, Korea
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For decades, global printed circuit board (PCB) market has been continuously expanded due to increasing demand of smart devices. Also, PCB became smaller and thinner than before, which resulted in multi-layered flexible printed circuit board (FPCB). Conventionally, multi-layered FPCB was manufactured through a photolithography method. However, the photolithography method has serious drawbacks, such as long tact time, use of toxic chemicals, and high cost. Therefore, a printed electronics technique was considered as an alternative technique, which consists of three simple processes: printing, sintering, and inspection. This technique enables fabrication of electronic devices with short process time, low cost, and environmentally friendliness. Once this technique is combined with a flash light sintering method, it can be a powerful process for the fabrication of multi-layered FPCB. The flash light sintering method uses xenon lamp that irradiates intensive white light, various nano/micro materials can be sintered in a few milliseconds under room temperature and ambient condition. However, there is no study considering printabillity and sinterbility of inks in multi-layered PCB with via-holes. Therefore, in this work, rheological property and flash light sintering characteristics of Cu/Ag hybrid-ink were simultaneously investigated for multi-layered FPCB application. Cu/Ag hybrid-inks were fabricated with various epoxy content, then the fabricated inks were printed on via-hole formed in polyimide substrate to analyze printing characteristics according to the rheology of ink. The printed Cu/Ag hybrid-ink was subsequently sintered by using flash light sintering method with various irradiation conditions including irradiation energy, pulse number, and pulse duration. The sintered Cu/Ag hybrid-inks were characterized using a scanning electron microscopy (SEM) and X-ray photoelectron spectroscopy (XPS). From these results, it was found that the Cu/Ag hybrid-ink with optimal ratio of epoxy binder content showed high printability, and the optimized multi-pulse flash light irradiation condition (irradiation energy: 7 J/cm2, and pulse duration: 1 ms, off-time: 9 ms and pulse number: 20) exhibited high conductivity (pattern: 9.52 μٞcm, via-hole: 12.69 μٞcm) and high adhesion strength (5B) with well-sintered morphology.