AVS 62nd International Symposium & Exhibition | |
Plasma Science and Technology | Tuesday Sessions |
Session PS+BI+SM-TuM |
Session: | Plasmas for Medicine and Biological Applications |
Presenter: | Vladimir Milosavljevic, Dublin Institute of Technology, Ireland |
Authors: | V. Milosavljevic, Dublin Institute of Technology, Ireland J. Lalor, Dublin Institute of Technology P. Bourke, Dublin Institute of Technology P.J. Cullen, Dublin Institute of Technology |
Correspondent: | Click to Email |
Atmospheric pressure, non-thermal plasma DBD is increasingly used in many processing applications. Despite their widespread usage, it remains largely unknown whether cold atmospheric plasma DBD maintains similar characteristics, such as gas temperatures and particle flux, when they breakdown while arcing or whether they possess different operating modes. It is essential for laboratory/industrial adoption of such plasmas that plasma diagnostics of the process are provided. Optical emission and absorption spectroscopy have been used as diagnostics techniques with an added avantage of their non-intrusive nature.
The type of operating gas influences the stability of atmospheric plasma discharges. In this study is used a sealed meat package filled with one of two gas mixtures: O2-CO2 and N2-CO2 . Different concentrations of nitrogen or oxygen and carbon-dioxide could cause the transition from a stable homogeneous discharge into a filamentary discharge. Atmospheric plasma discharges are affected by the surrounding ambient air, and for sealed packages from transfer between the package gas and the surrounding ambient atmosphere. In the vast majority of atmospheric plasma discharges, reactive nitrogen species dominates the ionic composition of atmospheric discharge and has an impact on the breakdown voltage. When N2 is added/mixed with CO2 plasma discharges, the CO2 emission lines are significantly quenched. In the case of O2-CO2 chemistry, nitrogen is not a carrier gas but it still present in the package due to contaminant transfer with the surrounding ambient air, modifying the plasma chemistry in the package. The plasma’s optical spectrum in O2-CO2 chemistry shows molecular oxygen, nitrogen and OH peaks. Oxygen could come from the ambient air, the O2-CO2 gas mixture or from humidity in the package. Electron impact excitation of molecular oxygen, at low collision energies, is of particular importance because of its role in atmospheric physics and has been objective of this study. In our study we have also recorded the O3 band-head that belongs to the Hartley Band. Ozone plays very important role for the biological aspect of this study and shows the highest change in a concentration with the processing time. Combining the results from spectral radiation in the package provides an electron energy distribution function. The study includes a detailed experimental investigation of the spatial and temporal spectroscopic data and links them with plasma kinetics.
The research leading to these results has received funding from the European Union´s Seventh Framework Programme managed by REA Research Executive Agency (FP7/2007-2013) under Grant Agreement number 605125.