AVS 58th Annual International Symposium and Exhibition
    Plasma Science and Technology Division Tuesday Sessions
       Session PS+MN+TF-TuM

Invited Paper PS+MN+TF-TuM1
Scallop Free TSV Etching Method for 3-D LSI Integration

Tuesday, November 1, 2011, 8:00 am, Room 202

Session: Plasma Processing for Disruptive Technologies
Presenter: Yasuhiro Morikawa, ULVAC, Inc., Japan
Authors: Y. Morikawa, ULVAC, Inc., Japan
T. Murayama, ULVAC, Inc., Japan
T. Sakuishi, ULVAC, Inc., Japan
S. Toyoda, ULVAC, Inc., Japan
K. Suu, ULVAC, Inc., Japan
Correspondent: Click to Email

Thru silicon via (TSV) etch process for deep and high-aspect ratio structure has been studied thoroughly for applications such as MEMS and CMOS devices. Recently, TSV used in 3D-LSI devices for logic devices may be a few microns in diameter and about 50 um deep. On the other hand, TSVs used in stacking memory devices, the via diameter and depth would be several tens of microns. Therefore, development of TSV etching process is very important for realizing these applications. In this study, a large via size etching in a high-pressure process was focused by using very high frequency capacitive coupled plasma (VHF –CCP) with an ultra self-confined system. This plasma system is simple parallel plate CCP about 100Pa or more process. High-pressure process was carried out on the plasma confined, because mean free pass is very short. And, ion energy distribution (IED) is also controllable by high-presser process with VHF bias. The bimodal IED changes under high-pressure. The peak of high-energy side is reduced, and a charge exchange peak appears. It is considered that the charge exchange is important to anisotropic Si etching of large size TSV with VHF bias.

And next, the high-density and small size of TSV below 10um diameter is indispensable to the utilization and improvement in high performance of 3D-LSI. We have developed a new etching system for TSV application for small size and high aspect ratio via. This system is a planer type magnetic neutral loop discharge (NLD) plasma. For high rate silicon etching, it is very important to understand not only the high density of the ICP plasma generation but also the high density of fluorine atoms. In this study, a novel RF antenna ‘Multi Stacked rf Antenna’ has been developed for highly accurate and high rate etching process. This antenna consists of multistage spiral turn rf antennas to reduce self-inductance (L). The L of this antenna is below 1.0 uH and it is a lower than the standard spiral antenna. As a result of performing the electron density measurement of the planer NLD plasma using this MS antenna, it succeeded in the high-density plasma production of 1x1012 / cm3 by the process pressure of 7 Pa. Next, the Si etching process development was performed using the advanced NLD etcher. As a result, the etching rate improved 4 times more compared to the standard cylindrical NLD plasma. Finally, the diameter of 2um was attained by the anisotropic etching of 5 um/min, and the aspect ratio is above 10 using the planer NLD etcher. VHF CCP and planer NLD etching processes are non-cycle etch methods, and these processes were demonstrated about smooth sidewall TSV formation.