AVS 58th Annual International Symposium and Exhibition
    Spectroscopic Ellipsometry Focus Topic Thursday Sessions
       Session EL-ThP

Paper EL-ThP5
Combined Electrochemical Impedance Spectroscopy and In Situ Spectroscopic Ellipsometry of Anodically Grown SiO2

Thursday, November 3, 2011, 6:00 pm, Room East Exhibit Hall

Session: Spectroscopic Ellipsometry Poster Session
Presenter: Chad Briley, University of Nebraska - Lincoln
Authors: E.A. Montgomery, University of Nebraska - Lincoln
T.E. Tiwald, J.A. Woollam Co., Inc.
E. Schubert, University of Nebraska - Lincoln
M. Schubert, University of Nebraska - Lincoln
C. Beasley, Gamry Instruments
C. Briley, University of Nebraska - Lincoln
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Electrochemical oxidation of silicon (n-type) at room temperature in a mixture of ethylene glycol, water and potassium nitrate has been performed by applying constant current densities to prepare thin SiO2 layers. In-situ Electrochemical Impedance Spectroscopy (EIS) and Spectroscopic Ellipsometry (SE) are employed during the SiO2 film growth. Using EIS and SE techniques in-situ one is able to monitor the capacitive changes and also the film thickness change of the oxide. The thickness of the oxides is also measured ex-situ before and after growth using SE. Equivalent circuit models corresponding to the electrolyte-oxide-silicon interfaces and optical models are fit to EIS and SE data respectively, to gain insight into the quality of the anodically grown SiO2.