AVS 66th International Symposium & Exhibition
    Surface Science Division Thursday Sessions
       Session SS+AS+HC+TL-ThM

Invited Paper SS+AS+HC+TL-ThM1
Chemical and Electrochemical Stability of Perovskite Oxide Surfaces in Energy Conversion: Mechanisms and Improvements

Thursday, October 24, 2019, 8:00 am, Room A220-221

Session: Surface Science of Energy Conversion and Storage
Presenter: Bilge Yildiz, Massachusetts Institute of Technology
Correspondent: Click to Email
A broad range of highly active doped ternary oxides, including perovskites, are desirable materials in electrochemical energy conversion, catalysis and information processing applications. At elevated temperatures related to synthesis or operation, however, the structure and chemistry of their surfaces can deviate from the bulk. This can give rise to large variations in the kinetics of reactions taking place at their surfaces, including oxygen reduction, oxygen evolution, and splitting of H2O and CO2. In particular, aliovalent dopants introduced for improving the electronic and ionic conductivity enrich and phase separate at the surface perovskite oxides. This gives rise to detrimental effects on surface reaction kinetics in energy conversion devices such as fuel cells, electrolyzers and thermochemical H2O and CO2 splitting. This talk will have three parts. First, the mechanisms behind such near-surface chemical evolution will be discussed. Second, the dependence of surface chemistry on environmental conditions, including temperature, gas composition, electrochemical potential and crystal orientation will be described. Third, modifications of the surface chemistry that improve electrochemical stability and actvity, designed based on the governing mechanisms, will be presented. Guidelines for enabling high performance perovskite oxides in energy conversion technologies will be presented.