AVS 65th International Symposium & Exhibition | |
Surface Science Division | Thursday Sessions |
Session SS+AS+BI+MI+NS-ThA |
Session: | Organic/Inorganic Surfaces, Interfaces and Nanostructures |
Presenter: | Christine Cheng, University of Southern California |
Authors: | C. Cheng, University of Southern California M. Gupta, University of Southern California |
Correspondent: | Click to Email |
Porous materials are used in various applications including separation membranes, paper-based microfluidics, and flexible electronics. Tuning surface properties of porous materials enhances the versatility of existing materials, giving them new functions and applications. However, traditional surface modification methods are typically solvent-based, which limits the range of substrates that can be coated. In this work, initiated chemical vapor deposition was used to continuously modify the surface of large areas of porous substrates in an all-dry vacuum process. A superhydrophobic polymer was deposited onto a porous substrate and the coating was characterized using contact angle goniometry, X-ray photoelectron spectroscopy, and scanning electron microscopy to study the uniformity of the coating along the entirety of the substrate. The superhyodrophobicty of the coated porous substrate is attributed to the deposited polymer and the roughness of the substrate. Addition of a perfluorinated liquid to the superhydrophobic porous substrate formed a slippery liquid-infused porous surface. A hydrophilic polymer was deposited on top of the superhydrophobic polymer to demonstrate the facile stacking of polymer layers with different chemistries using this process.