AVS 65th International Symposium & Exhibition
    Advanced Surface Engineering Division Monday Sessions
       Session SE-MoA

Invited Paper SE-MoA5
Metallic-Glass Nanotube Arrays: A Novel Device for Various Applications

Monday, October 22, 2018, 2:40 pm, Room 202C

Session: New Challenges and Opportunities in Surface Engineering
Presenter: Jinn P. Chu, National Taiwan University of Science and Technology, Taiwan, Republic of China
Authors: J.P. Chu, National Taiwan University of Science and Technology, Taiwan, Republic of China
J.K. Chen, National Taiwan University of Science and Technology, Taiwan, Republic of China
C.C. Yu, National Taiwan University of Science and Technology, Taiwan, Republic of China
Correspondent: Click to Email

A new group of thin film metallic glasses have been known to exhibit properties different from conventional crystalline metal films, though their bulk forms are already well-known for properties such as high strength because of their amorphous structure. We successfully fabricated the first-ever metallic glass nanotubes (MGNTs) on Si by a simple lithography and sputter deposition process for very large-scale integration. Like biological nanostructured surfaces, MGNTs show some surprising water repelling and attracting properties. Nanotubes are 500-750 nm tall and 500-750 nm in diameter, shown in Figure 1 [1]. The MGNT surface becomes hydrophobic, repelling water. By heating and cooling the array, water can be repelled and attached to the surface [1]. There are two examples presented in this talk based on modifications of this scheme. First, after modification of biotin, the array acts as a waveguiding layer for an optical sensor. The MGNT sensor waveguide could readily detect the streptavidin by monitoring the shift. The detection limit of the arrays for streptavidin is estimated to be 25 nM, with a detection time of 10 min. Thus, the arrays may be used as a versatile platform for high-sensitive label-free optical biosensing [2]. Second, the array is prepared on a heating device on Si and, with an applied electric voltage to the heating device underneath, the array surface was heated to generate an extending force from these nanochambers so that the array are functioned as biomimetic artificial suckers for thermally adhesion response in biological systems [3].

References

[1] J. K. Chen, W. T. Chen, C. C. Cheng, C. C. Yu and J. P. Chu, Metallic glass nanotube arrays: preparation and surface characterizations, Materials Today, 21 (2018), 178-185.

[2] W. T. Chen⁠, S. S. Li⁠, J. P. Chu⁠, K. C. Feng, J. K. Chen, Fabrication of ordered metallic glass nanotube arrays for label-free biosensing with diffractive reflectance, Biosensors and Bioelectronics, 102 (2018), 129-135.

[3] W. T. Chen, K. Manivannan, C. C. Yu, J. P. Chu and J. K. Chen, Fabrication of an artificial nanosucker device with a large area nanotube array of metallic glass, Nanoscale, 10 (2018) 1366-1375.