AVS 65th International Symposium & Exhibition
    Actinides and Rare Earths Focus Topic Thursday Sessions
       Session AC-ThA

Invited Paper AC-ThA3
Improving the Understanding of Actinides Through Spectroscopy

Thursday, October 25, 2018, 3:00 pm, Room 202C

Session: Early Career Scientists
Presenter: Samantha Cary, Los Alamos National Laboratory
Authors: S.K. Cary, Los Alamos National Laboratory
J. Su, Los Alamos National Laboratory
S.S. Galley, Florida State University
T.E. Albrecht-Schmitt, Florida State University
E. Batista, Los Alamos National Laboratory
M.G. Ferrier, Los Alamos National Laboratory
S.A. Kozimor, Los Alamos National Laboratory
V. Mocko, Los Alamos National Laboratory
B.L. Scott, Los Alamos National Laboratory
B.W. Stein, Los Alamos National Laboratory
F.D. White, Florida State University
P. Yang, Los Alamos National Laboratory
Correspondent: Click to Email

Understanding the fundamental aspects of bonding is important in predicting an element's behavior, unfortunately when it comes to the actinides, there is little known. Acquiring a better understanding of these elements will affect a number of different areas including nuclear forensics, national security, and nuclear fuel cycles. Here we will describe the preparation of M(S2CNEt2)3(X) (MIII = Nd, Sm, Eu, Gd, Am, Cm, and Cf; X = n-heterocyclic aromatic ligands) and compare their structure, X-ray absorption spectroscopy, and electronic structure calculations.