AVS 65th International Symposium & Exhibition
    Actinides and Rare Earths Focus Topic Thursday Sessions
       Session AC+AS+SA-ThM

Paper AC+AS+SA-ThM13
Physicochemical Properties of Ag in Annealed ZrN/SiC/Ag Heterostructures Used to Simulate TRISO Nuclear Fuels

Thursday, October 25, 2018, 12:00 pm, Room 202C

Session: Nuclear Power, Forensics, and Other Applications
Presenter: Jeff Terry, Illinois Institute of Technology
Authors: J. Terry, Illinois Institute of Technology
M. Warren, Illinois Institute of Technology
R. Seibert, Illinois Institute of Technology
Correspondent: Click to Email

Silicon carbide (SiC) is used as a supportive and protective barrier in the cladding of tristructural-isotropic (TRISO) nuclear fuel particles. Previous studies both of surrogate surfaces and irradiated fuel have shown that the fission product silver (Ag) exhibits transport into and sometimes through the SiC barrier with temperatures above 500 °C. This silver release can cause safety concerns for maintenance workers due to plate-out on in-reactor components. Although an exact diffusion mechanism for Ag in SiC is unknown, a solution is needed to prevent this effect. The use of a ZrN protective coating may mitigate Ag transport and potential release. This study examines the transport of Ag in SiC through the use of surrogate multilayered thin-films. Thin films of subsequent layers of SiC, Ag, SiC, and ZrN deposited by pulsed-laser ablation deposition (PLD) under a range of annealing temperatures up to 1200 °C are studied. After heating, X-ray photoemission spectroscopy (XPS), scanning electron microscopy (SEM), and energy-dispersive X-ray spectroscopy (EDS) was used to examine the surface of the ZrN. Initial results show that Ag does not readily diffuse through the ZrN layer like it does through SiC. The results and implications of this study will be discussed.