AVS 64th International Symposium & Exhibition
    Electronic Materials and Photonics Division Thursday Sessions
       Session EM-ThP

Paper EM-ThP4
Optical and Magneto-optical Properties of Zn1-xCoxO / ZnO Hollow Nanospheres

Thursday, November 2, 2017, 6:30 pm, Room Central Hall

Session: Electronic Materials and Photonics Poster Session
Presenter: Da-Ren Liu, Instrument Technology Research Center, National Applied Research Laboratories
Authors: D.R. Liu, Instrument Technology Research Center, National Applied Research Laboratories
C.J. Weng, Instrument Technology Research Center, National Applied Research Laboratories
Correspondent: Click to Email

Diluted magnetic semiconductors (DMS) have attracted considerable attention due to their potential applications for spintronic devices, such as spin-valve transistors, nonvolatile memory, and magneto-optical switches. ZnCoO is one of the most promising DMS materials due to its predicted above room temperature ferromagnetism. In this study, ZnO layer was conformally deposited on the surface of polystyrene (PS) nanoshperes with different diameter (100nm~800nm) by atomic layer deposition (ALD). Then the Zn1-xCoxO (0.01 < x < 0.1) coatings were grown on ZnO hollow nanospheres by pulsed laser deposition(PLD). According to the results of high-resolution x-ray diffraction, Co-doping does not change the wurtzite structure of ZnO and the Zn1-xCoxO/ZnO hollow nanospheres are polycrystalline. Photoluminescence spectra and transmittance show an increase of the band gap with increasing Co ion concentration. The temperature-dependent magnetization (M-T) curves of the Zn1-xCoxO/ZnO hollow nanospheres were measured by a superconducting quantum interference device (SQUID) magnetometer and the magneto-optical properties were measured by micro-MOKE spectroscopy. The results show the magneto-optical properties of the Zn1-xCoxO/ZnO hollow nanospheres depend on the Co composition fraction and the size of nanospheres.