AVS 63rd International Symposium & Exhibition
    Surface Science Tuesday Sessions
       Session SS1+AS+HC+NS-TuM

Paper SS1+AS+HC+NS-TuM4
Hyperthermal Ion Induced Hot Carrier Excitations in a Metal Probed using Schottky Diodes

Tuesday, November 8, 2016, 9:00 am, Room 104D

Session: Surface Dynamics, Non-Adiabaticity, and Theory and Modeling of Surface and Interfacial Phenomena
Presenter: Dhruva Kulkarni, Clemson University
Authors: D.D. Kulkarni, Clemson University
D.A. Field, Clemson University
D.B. Cutshall, Clemson University
J.E. Harriss, Clemson University
W.R. Harrell, Clemson University
C.E. Sosolik, Clemson University
Correspondent: Click to Email

We present measurements on hot carrier excitations in a metal irradiated by hyperthermal energy ions.

Specifically, alkali (Na+/Rb+) and noble gas(Arq+) ions were used to irradiate a Schottky diode consisting of

a thin film of Ag (~25nm) grown on an n-type Si (111) wafer. Measurements of the resultant current

through the device were performed as a function of energy, angle of incidence and velocity of the

incident ions. Energy loss of the incident energetic ions inside the metal film leads to the generation of

hot carriers that travel ballistically to the Schottky interface and are detected as a kinetically-induced

current or “kinecurrent” within the device. This kinecurrent is analogous to previous measurements of

“chemicurrent” [H. Nienhaus, Surface Science, 45, 1-78 (2002)], which were linked to the energy

delivered to a surface by exothermic reactions that could non-adiabatically couple to the electronic

structure and generate hot carriers.