AVS 63rd International Symposium & Exhibition
    Advanced Surface Engineering Tuesday Sessions
       Session SE+NS+TF+TR-TuM

Paper SE+NS+TF+TR-TuM5
Improved Mechanical Properties In Tungsten-Molybdenum Nanostructured Thin Films

Tuesday, November 8, 2016, 9:20 am, Room 101C

Session: Nanostructured Thin Films and Coatings
Presenter: Gustavo Martinez, University of Texas at El Paso
Authors: G. Martinez, University of Texas at El Paso
C.V. Ramana, University of Texas at El Paso
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Preventing materials failure and improving the performance of materials in nuclear reactors demand novel materials to serve under extreme environment conditions. For nuclear applications, tungsten (W) has been alloyed in the past with La and Re to improve its performance and properties including low fracture and high ductile to brittle transition. In this work, molybdenum (Mo) solute atoms were added to W matrix with the intention of creating interstitial point defects in the crystals that impede dislocation motion, increasing the hardness and young modulus of the material. Nanostructured W-Mo thin films with variable Mo content were deposited by the sputter-deposition. W-Mo films were stabilized in bcc structure of W. Studies showed that as grain size formation increases the residual stress distribution will reach the maximum and stabilize after a deposition temperature of 350 °C. The residual stress still continues to follow a parabolic pattern, indicating that the stresses mainly depend on grain organization rather than atomic packing. From Nano-scratch testing, it is found that depth penetration decreases with increasing sputtering temperature. The effect of Mo on the overall mechanical properties improvement in W-Mo nanostructured thin films will be presented and discussed.

Keywords: Tungsten-Molybdenum Thin Films, Mechanical Properties, Nano-Indentation