AVS 63rd International Symposium & Exhibition
    Nanometer-scale Science and Technology Monday Sessions
       Session NS-MoA

Paper NS-MoA2
The Effects of N Incorporation in GaAsSb/GaAs Core-shell Nanowires

Monday, November 7, 2016, 2:00 pm, Room 101D

Session: Nanophotonics, Plasmonics, and Energy
Presenter: Prithviraj Deshmukh, NCA&T State University
Authors: P. Deshmukh, NCA&T State University
P. Kasanaboina, NCA&T State University
C. Reynolds Jr., North Carolina State University
Y. Liu, North Carolina State University
S. Iyer, NCA&T State University
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Bandgap tuning beyond 1.3 µm in GaAsSb based nanowires by incorporation of dilute amount of N is reported, for realizing nanoscale optoelectronic devices in the telecommunication wavelength region. Vertical GaAs/GaAsSbN/GaAs core-shell configured nanowires are grown on Si (111) substrates using plasma assisted molecular beam epitaxy. Effects of N incorporation and thickness of the shell layers on the micro-photoluminescence spectral peak shifts have been studied. Annealing in N2 ambient led to enhanced spectral intensity, which is attributed to the annihilation of defects. Shifts and changes in the spectral shapes of the Raman spectra prior to and after annealing have been used to ascertain the nature of the defects being annihilated during the growth. I-V measurements also provided further support to the annihilation of predominantly point defects on annealing. Results from the transmission electron microscopy study on the planar defects will also be presented.