AVS 63rd International Symposium & Exhibition | |
2D Materials Focus Topic | Wednesday Sessions |
Session 2D+NS-WeA |
Session: | Nanostructures including Heterostructures made of 2D Materials |
Presenter: | Jeff Terry, Illinois Institute of Technology |
Authors: | J. Terry, Illinois Institute of Technology D. Velazquez, Illinois Institute of Technology R. Seibert, Illinois Institute of Technology L. Spentzouris, Illinois Institute of Technology |
Correspondent: | Click to Email |
We have grown thin films of hexagonal boron nitride (h-BN) of thickness 1-10 ML on fiber-oriented Ag buffer films on SrTiO3(001) by pulsed laser deposition. We used Ag buffer films of 40nm thickness to substitute for expensive single crystal metallic substrates. Reflection high-energy electron diffraction (RHEED) was used to monitor the surface structure of the Ag films and to observe the formation of the characteristic h-BN diffraction pattern. Attenuated total reflectance spectroscopy showed the characteristic h-BN peaks at 780 cm-1 and 1367.4 cm-1. Ex-situ photoelectron spectroscopy showed that the surface of the h-BN films was stoichiometric. Scanning electron microscopy showed that the h-BN films grew as large, sub-millimeter sheets with nano- and micro-sheets scattered on the surface. The h-BN sheets was easily exfoliated by the micromechanical adhesive tape method. The use of thin film Ag allowed us to adjust the surface morphology of the thin film prior to h-BN growth.