AVS 63rd International Symposium & Exhibition
    2D Materials Focus Topic Wednesday Sessions
       Session 2D+NS-WeA

Paper 2D+NS-WeA7
Pulsed Laser Deposition of Single Layer, Hexagonal Boron Nitride on Fiber-oriented Ag(111)/SrTiO3(001)

Wednesday, November 9, 2016, 4:20 pm, Room 103B

Session: Nanostructures including Heterostructures made of 2D Materials
Presenter: Jeff Terry, Illinois Institute of Technology
Authors: J. Terry, Illinois Institute of Technology
D. Velazquez, Illinois Institute of Technology
R. Seibert, Illinois Institute of Technology
L. Spentzouris, Illinois Institute of Technology
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We have grown thin films of hexagonal boron nitride (h-BN) of thickness 1-10 ML on fiber-oriented Ag buffer films on SrTiO3(001) by pulsed laser deposition. We used Ag buffer films of 40nm thickness to substitute for expensive single crystal metallic substrates. Reflection high-energy electron diffraction (RHEED) was used to monitor the surface structure of the Ag films and to observe the formation of the characteristic h-BN diffraction pattern. Attenuated total reflectance spectroscopy showed the characteristic h-BN peaks at 780 cm-1 and 1367.4 cm-1. Ex-situ photoelectron spectroscopy showed that the surface of the h-BN films was stoichiometric. Scanning electron microscopy showed that the h-BN films grew as large, sub-millimeter sheets with nano- and micro-sheets scattered on the surface. The h-BN sheets was easily exfoliated by the micromechanical adhesive tape method. The use of thin film Ag allowed us to adjust the surface morphology of the thin film prior to h-BN growth.