AVS 62nd International Symposium & Exhibition
    Surface Science Tuesday Sessions
       Session SS+AS+EN+NS-TuM

Paper SS+AS+EN+NS-TuM6
Growth and Intercalation of Cu and Dy on the Basal Plane of Graphite

Tuesday, October 20, 2015, 9:40 am, Room 112

Session: Nanostructures, Nanoplasmonics and Surface Reactions
Presenter: Patricia A. Thiel, Iowa State University
Authors: P.A. Thiel, Iowa State University
D. Appy, Iowa State University
E.J. Kwolek, Iowa State University
D. Shao, Iowa State University
M. Wallingford, Iowa State University
M.C. Tringides, Iowa State University
J.W. Evans, Iowa State University
Y. Han, Iowa State University
H. Lei, Institute of Solid State Physics, CAS, China
C.-Z. Wang, Iowa State University
Correspondent: Click to Email

Graphite, and surface processes on graphite, serves as a valuable benchmark for carbon-based materials such as graphene. We have studied copper and dysprosium on graphite, deposited by an e-beam evaporator in UHV and imaged with STM, to determine the characteristic features of nucleation and growth of metal islands. One of the fundamental questions that arises naturally is whether metal nucleates homogeneously on the terraces or whether it nucleates heterogeneously at defect sites. To answer this question we employ several tools, especially a comparison between high-level van der Waals theory for single atom diffusion, and measured island density. We also present evidence for unexpected metal intercalation at the surface of graphite, after treatment at elevated temperature.