AVS 62nd International Symposium & Exhibition
    Surface Science Tuesday Sessions
       Session SS+AS+EN+NS-TuM

Paper SS+AS+EN+NS-TuM2
ENDOM: A Simple Method to Deposit Nanostructures from Nanowires to Nanopores

Tuesday, October 20, 2015, 8:20 am, Room 112

Session: Nanostructures, Nanoplasmonics and Surface Reactions
Presenter: Ashley Ellsworth, University of Texas at Dallas
Authors: A.A. Ellsworth, University of Texas at Dallas
A.V. Walker, University of Texas at Dallas
Correspondent: Click to Email

A key challenge in the practical application of nanostructures is their effective integration through assembly, patterning and alignment on technologically relevant substrates. We have recently demonstrated a new technique, electroless nanowire deposition on micropatterned substrates (ENDOM), by which to simultaneously synthesize and place nanowires on chemically patterned substrates. The nanowires can be precisely oriented on the surface in arbitrary shapes, such as an arch and around a right angle bend. In ENDOM, the shape of the deposit is controlled by the substrate pattern while its width is controlled by the reaction conditions. By employing longer deposition times and the appropriate substrate patterns, nanopores and nanochannels can be produced. However for sensing and nanoelectronic applications, free standing nanopores and nanochannels are generally employed. We have observed that the nanostructure adhesion to the surface is dependent upon the reagent concentrations. For example in Cu ENDOM, upon reduction of triethanolamine (complexing agent and buffer) concentration, nanowires no longer adhere strongly to the substrate and can be transferred to another substrate. In this presentation, we shall discuss the mechanisms of adhesion, transfer of these nanostructures to other substrates and proof-of-concept studies to synthesize free-standing nanostructures.