AVS 61st International Symposium & Exhibition
    Surface Science Thursday Sessions
       Session SS+TF-ThM

Paper SS+TF-ThM10
CuPc:C60 Composite Films: From Sub–Monolayer to Multi-Layer Growth

Thursday, November 13, 2014, 11:00 am, Room 309

Session: Organic Layers on Surfaces
Presenter: Taylor Stock, University of Toronto, Canada
Authors: T.J.Z. Stock, University of Toronto, Canada
J. Nogami, University of Toronto, Canada
Correspondent: Click to Email

CuPc:C60 composite films of various compositions and thicknesses grown on the Cu(111) surface have been studied using room temperature scanning tunneling microscopy (STM) and scanning tunneling spectroscopy (STS). At coverages below two monolayers (ML), phase segregated, ordered films, or well mixed, disordered films can be produced depending on the particular deposition sequence. This compositional variability is achieved by exploiting the differences in the relative strengths of the various molecule-substrate and molecule-molecule interaction forces. In thicker films, the CuPc-C60 intermolecular interaction dominates the growth, and for a range of concentrations these films are found to be well mixed, amorphous and thermally stable. These results provide a rationale for improvements that have been seen for organic light emitting diode (OLED) performance associated with C60 doping of CuPc molecular layers. [1]


[1] Y. Y. Yuan, S. Han, D. Grozea, and Z. H. Lu, Appl. Phys. Lett. 88, 093503 (2006).