AVS 60th International Symposium and Exhibition
    Ions at Aqueous Interfaces Focus Topic Monday Sessions
       Session IA+AI+BI+IS+NL+SS-MoA

Paper IA+AI+BI+IS+NL+SS-MoA7
Molecular Insight Into the Preferential Adsorption of Monovalent Ions to Selected Polar Surfaces: A Vibrational Sum Frequency Study

Monday, October 28, 2013, 4:00 pm, Room 203 A

Session: Ions at Aqueous Interfaces
Presenter: E.C. Tyrode, KTH Royal Institute of Technology, Sweden
Authors: E.C. Tyrode, KTH Royal Institute of Technology, Sweden
R. Corkery, KTH Royal Institute of Technology, Sweden
Correspondent: Click to Email

Vibrational Sum Frequency Spectroscopy (VSFS) has been used to systematically study the preferential adsorption of a series of monovalent ions to charged and uncharged fatty acid monolayers. Ion enrichment is mainly determined indirectly by targeting surface water vibrational modes. In selected cases however, the ion presence is also directly determined by targeting the fatty acid carboxylate headgroups. A major effort is made to understand the effect of co-ions in the molecular properties of these biophysically relevant interfaces.