AVS 59th Annual International Symposium and Exhibition
    Graphene and Related Materials Focus Topic Wednesday Sessions
       Session GR+AS+EM+NS+SS-WeA

Paper GR+AS+EM+NS+SS-WeA7
Metal Oxide Growth and Characterization on CVD Graphene

Wednesday, October 31, 2012, 4:00 pm, Room 13

Session: Dopants and Defects in Graphene; Graphene Interfaces with Other Materials
Presenter: A. Matsubayashi, College of Nanoscale Science and Engineering, University at Albany
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Thin metal oxide layers deposited on graphene can be utilized as dielectric barriers between metals and graphene to help isolate a metal contact from the graphene channel. This is important for graphene based spintronic devices as dielectric layers between the ferromagnetic electrode and graphene have been shown to increase the spin relaxation time measured utilizing non-local detection and spin precession measurements[1]. However, simply depositing metal oxide layers such as aluminum oxide on graphene results in non-uniform film lowering the quality of the interface barrier[2]. In addition it is important to understand the stoichiometry of the resulting film. We will present a systematic study of aluminum oxide layers grown on CVD (chemical vapor deposition) graphene under ultra-high vacuum conditions with and without titanium seed layers. The aluminum oxide layers with the titanium seed layers showed reduced surface roughness. The chemical and structural composition determined by XPS (X-ray photoelectron spectroscopy) will be also presented that shows full oxidation of the aluminum and partial oxidation of the titanium.

References:

(1) E. I. Rashba, Phys. Rev. B, 62, 16267 (2000)

(2) W. Han et al, Phys. Rev. Lett., 105, 167202 (2010)