AVS 59th Annual International Symposium and Exhibition
    Electronic Materials and Processing Monday Sessions
       Session EM+TF+OX+GR-MoM

Paper EM+TF+OX+GR-MoM5
Interface Study of the Atomic Layer Deposited Al2O3 on Al0.25Ga0.75N

Monday, October 29, 2012, 9:40 am, Room 009

Session: High-k Dielectrics for MOSFETs I
Presenter: X. Qin, The University of Texas at Dallas
Authors: X. Qin, The University of Texas at Dallas
B. Brennan, The University of Texas at Dallas
H. Dong, The University of Texas at Dallas
R.M. Wallace, The University of Texas at Dallas
Correspondent: Click to Email

Due to the high two-dimensional electron gas (2-DEG) density, AlGaN/GaN high electron mob­­­i­l­i­t­­y transistors (HEMTS) are recognized as key devices for high power and low noi­s­e ap­p­l­­ic­a­tions. However, the associated large gate leakage current degrades the performance of AlGaN­ HE­M­­Ts. In order to solve this problem, MOS-HEMTs have been developed, in which the incorporation of a high-k gate di­e­l­e­ctric ­l­a­yer can overcome the drawbacks.

In this work, the native and treated Al0.25Ga0.75N surface chemical states and structure of were studied by x-ray photoele­c­t­ron spectroscopy (XPS), ion scattering spectroscopy (ISS) and l­o­w ene­r­gy electron diffraction. Different chemical treatment processes including (NH4)OH, (NH4)2S and HF were studied, followed by atomic layer deposition (ALD) Al2O3 layers on Al0.25Ga0.75N . T­he oxidation states of the Al0.25Ga0.75Ninterface and Al2O3 deposition process were st­udied b­y in-situ XPS analysis. In addition, ex-situ atomic force microscopy (AFM) was used to obs­e­rve the surf­­a­ce topography before and after the Al2O3 deposition. According to the XPS results, it is found that chemical treatments could remove the native Al2O3 but were not effective to eliminate the Ga oxide, and the growth rate of Al2O3 is low on the native and treated Al0.25Ga0.75N samples. The AFM images show that there are many pin holes in the surface of Al0.25Ga0.75N. Studies of HfO2 deposition will also be presented.

This work is supported by the AOARD under AFOSR Grant No. FA2386-11-1-4077