AVS 57th International Symposium & Exhibition
    Nanometer-scale Science and Technology Tuesday Sessions
       Session NS-TuP

Paper NS-TuP7
Spinel MxCo3-xO4 Nanoparticles: Facile Low Temperature Solution Synthesis and Characterization

Tuesday, October 19, 2010, 6:00 pm, Room Southwest Exhibit Hall

Session: Nanometer-Scale Science and Technology Poster Session
Presenter: D. Davis, Sandia National Laboratories
Authors: D. Davis, Sandia National Laboratories
M. Bencomo, Sandia National Laboratories
T.N. Lambert, Sandia National Laboratories
P. Lu, Sandia National Laboratories
S. Limmer, Sandia National Laboratories
W.G. Yelton, Sandia National Laboratories
Correspondent: Click to Email

The synthesis and characterization of spinel MxCo3-xO4 (M = Mn, Fe, Ni, Cu) nanoparticles was undertaken. Cobalt oxide-based nanoparticles doped with transition metals have a wide variety of potential applications, ranging from new material coatings for concentrating solar power applications to performing as cathode catalysts in fuel cells and metal-air batteries. We have recently demonstrated that MxCo3-xO4 nanoparticles can be prepared using simple, low temperature solution precipitation methods, and that the final size and morphology of the nanoparticle depends on the extent of doping. These materials have been characterized by powder X-ray diffraction (P XRD), high-resolution transmission electron microscopy (HR-TEM), N2 adsorption-desorption, and thermal gravimetric analysis/differential thermal analysis ( TGA/DTA). The synthesis, characterization, as well as some potential applications of these materials, will be presented.

This work is supported by the Department of Energy, Office of Basic Energy Science and the United States Department of Energy under contract number DE-AC04-94AL85000. Sandia is a multi-program laboratory operated by Sandia Corporation, a Lockheed-Martin Company, for the United States Department of Energy.