AVS 57th International Symposium & Exhibition
    Nanometer-scale Science and Technology Tuesday Sessions
       Session NS-TuP

Paper NS-TuP23
Role of the pH Obtaining Microstructures and Size-Controlled SnO2 Nanocrystals by the Precipitation Method

Tuesday, October 19, 2010, 6:00 pm, Room Southwest Exhibit Hall

Session: Nanometer-Scale Science and Technology Poster Session
Presenter: A. Pérez-Centeno, Universidad de Guadalajara, Mexico
Authors: C.E. Marín-Pineda, Universidad de Guadalajara, Mexico
M.A. Santana-Aranda, Universidad de Guadalajara, Mexico
C.R. Michel-Uribe, Universidad de Guadalajara, Mexico
G. Gómez-Rosas, Universidad de Guadalajara, Mexico
O.E. Contreras-López, Universidad Nacional Autonoma de Mexico
A. Pérez-Centeno, Universidad de Guadalajara, Mexico
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In this work we present the results of the pH effect on the synthesis of Sn02 by precipitation. This simple chemical route allowed us to obtain Sn02 nanocrystals whose grain size depends linearly on the pH, ranging from 3 to 8nm, from basic to acid solutions, respectively. The most important, microstructures were also fabricated by this simple method, mainly whiskers and long fibers. The crystalline quality and the morphology were confirmed by X-ray diffraction and electron microscopy. The samples showed high-energy optical absorption as observed by UV-Vis measurements.

Aknowledgements:

The technical support of Israel Gradilla and Francisco Ruiz are greatly acknowledged. This work was partially supported by PROMEP (projects 103.5/07/2636 and 103.5/08/2919) and COECYTJAL (project PS-2009-873).