AVS 57th International Symposium & Exhibition
    Magnetic Interfaces and Nanostructures Tuesday Sessions
       Session MI+EM-TuA

Paper MI+EM-TuA9
Chemical Switching of Coupled Molecular Spins: On and Off

Tuesday, October 19, 2010, 4:40 pm, Room Zuni

Session: Spintronics
Presenter: N. Ballav, Paul Scherrer Institute, Switzerland
Authors: C. Waeckerlin, Paul Scherrer Institute, Switzerland
D. Chylarecka, Paul Scherrer Institute, Switzerland
A. Kleibert, Paul Scherrer Institute, Switzerland
K. Mueller, Paul Scherrer Institute, Switzerland
C. Iacovita, University of Basel, Switzerland
F. Nolting, Paul Scherrer Institute, Switzerland
T.A. Jung, Paul Scherrer Institute, Switzerland
N. Ballav, Paul Scherrer Institute, Switzerland
Correspondent: Click to Email

Herein we present a unique approach to reversibly control between the on and off state of the spin of an organometallic molecule coupled to a ferromagnetic substrate by a chemical switch. Such an ultimate degree of control was achieved via modification of the coordination strength of the central metal ion of the organometallic molecule by an external ligand. Thus the regulation of oxygen affinity in hemoglobin by iron-porphyrin moiety as shown in nature has been used as a designed concept to perform the switching event of single molecular spin. Use of external stimuli to control single molecular spins at magnetic-interfaces is of potential interest for spintronics and quantum information.