AVS 47th International Symposium
    Processing at the Nanoscale/NANO 6 Thursday Sessions
       Session NS+NANO6-ThM

Invited Paper NS+NANO6-ThM3
Quantum-Coherence and Self-Assembly of Metallic Nanostructures

Thursday, October 5, 2000, 9:00 am, Room 302

Session: Nanostructured Materials
Presenter: H. Brune, Ecole Polytechnique Federale de Lausanne, Switzerland
Correspondent: Click to Email

We will discuss several means for the self-assembly of metallic islands of well defined size and mutual distance. The surface states of the (111)-oriented transition metal surfaces have extremely small Fermi vectors leading to long wavelength quantum-interference patterns. For Cu/Cu(111) these Friedel oscillations give rise to long range oscillatory adsorbate-adsorbate interactions which can be used to arrange adatoms or islands in hexagonal patterns. The period of these superlattices is @lambda@@sub F@/2 and thus coherently reflects the surface electronic properties. We then present the growth of nanostructure arrays using kinetically controlled growth on dislocation networks serving as templates. The mean size of the Ag, Fe, and Co dots is adjusted by the coverage. Their size distribution is given by the statistics of deposition. It has a half width at half maximum of 12% at 0.10ML, which is competitive with state-of-the-art semiconductor quantum dots, and goes down to 4% at 0.5ML. Small Co islands with well defined sizes can be created through coarsening by cluster diffusion on Pt(111). Since each cluster size has its own onset temperature for diffusion one can deliberately adjust the mean island size by the annealing temperature giving rise to high densities of very small islands ideally suited to investigate size-effects on reactivity and magnetic moment per atom.