AVS 64th International Symposium & Exhibition
    Tribology Focus Topic Thursday Sessions
       Session TR+AC+TF+VT-ThM

Paper TR+AC+TF+VT-ThM3
Role of Deuterium and Hydrogen in the Physical Understanding of Nano-friction in a-C:H/D Thin Films

Thursday, November 2, 2017, 8:40 am, Room 10

Session: Lubricant, Coatings, and Biotribology
Presenter: Carlos Figueroa, UCS, Brazil
Authors: F.G. Echeverrigaray, UCS, Brazil
S.R. Sales de Mello, UCS, Brazil
A.F. Michels, UCS, Brazil
F. Alvarez, UNICAMP, Brazil
C.A. Figueroa, UCS, Brazil
Correspondent: Click to Email

The friction phenomenon is a complex manifestation of the nature. In spite of phenomenological laws can describe the friction force at different scales, the fundamental physical understandings of such a phenomenon do not have consensus. Phenomena such as phononic, electronic, magnetic, and also electrostatic effects and models were developed in order to explain the meta- and nano-friction behavior of materials. In this work, we report the friction behavior of a diamond spherical dome sliding on different amorphous carbon thin films containing different amounts of hydrogen and/or deuterium inspecting at the meta-nanoscale indentation. Two important situation are reported. Firstly, for samples where hydrogen was replaced by deuterium in the thin film bulk, the friction coefficient decreases for increasing deuterium included in the carbon underneath structure. Secondly, for samples where hydrogen content is increased on the surface, the friction coefficient decreases with the increasing of the ratio H/C at the surface. In this paper, we discuss two different physical mechanisms describing these peculiar experimental results: dissipation effects associated with phonon coupling and van der Waals forces contributions coexisting and determining the friction behaviour of a-C:H/D for the cited studied situations.