| AVS 64th International Symposium & Exhibition | |
| 2D Materials Focus Topic | Tuesday Sessions |
| Session 2D+BI+MN+SS-TuA |
| Session: | Surface Chemistry, Functionalization, Bio and Sensor Applications |
| Presenter: | Keith Whitener, Naval Research Laboratory |
| Authors: | K.E. Whitener, Naval Research Laboratory W.-K. Lee, Naval Research Laboratory R. Stine, NOVA Research J.T. Robinson, Naval Research Laboratory D. Kidwell, Naval Research Laboratory C. Tamanaha, Naval Research Laboratory P.E. Sheehan, Naval Research Laboratory |
| Correspondent: | Click to Email |
Chemical functionalization can dramatically alter graphene’s properties, enabling one to tune its chemical and physical properties for a wide range of applications. To be useful, these modifications must be stable; however, some of these chemical modifications can be unstable, allowing the material to partially revert to unfunctionalized graphene over time. In this talk, we present our detailed studies of the kinetics of graphene hydrogenation and dehydrogenation. Single layer hydrogenated graphene can be dehydrogenated via thermal, mechanical, and chemical routes. Interestingly, bilayer graphene is much more robust to both chemical and thermal dehydrogenation than is single layer graphene. Possible mechanisms for this difference in reactivity will be discussed. Finally, we leverage the insights from these studies to first fabricate functional chemistries and electronic devices on graphene and then to transfer the devices in toto onto arbitrary substrates including biological ones. This enables graphene to act like a chemical “sticky note”, transferring chemical and physical properties from one surface to another.