AVS 62nd International Symposium & Exhibition | |
Spectroscopic Ellipsometry Focus Topic | Thursday Sessions |
Session EL+AS+BI+EM-ThA |
Session: | Optical Characterization of Nanostructures and Metamaterials |
Presenter: | Samuel O'Mullane, SUNY Polytechnic Institute |
Authors: | S. O'Mullane, SUNY Polytechnic Institute J. Race, Nanometrics N. Keller, Nanometrics A.C. Diebold, SUNY Polytechnic Institute |
Correspondent: | Click to Email |
For traditional ellipsometric targets, slightly changing the thickness of a layer or the index of refraction of a material results in a similarly small change in the observed spectra. If structures are designed to allow for plasmonic coupling, a slight change in those same parameters results in wildly different spectra. Specifically, localized plasmonic resonances in metallic grating structures allow for extraordinary sensitivity to parameters such as CD, sidewall angle and pitch.
Existing metallic grating structures are arrays of long, thin lines of copper that can be described using one dimension. The typical resolution for ellipsometric CD measurements on these structures ranges from nanometers to Ångströms. Because there is no confining second dimension, localized plasmons cannot be produced.
In order to obtain sub-Ångström resolution, additional structural modifications are required. This is achieved by adding a second metallic grating perpendicular to the original grating forming a cross-grating structure. Note that the added pitch and linewidth are an order of magnitude larger than the original parameters. This results in fully localized plasmonic resonances so that parameter variation on the order of tens of picometers could be detected through ellipsometric measurements. Making use of conical diffraction further increases the sensitivity to structural changes due to increased anisotropy.
These conclusions are the result of rigorous coupled wave-analysis (RCWA) simulations which were confirmed via finite element method (FEM) simulations. With both RCWA and FEM agreement, experimental confirmation is expected.