AVS 62nd International Symposium & Exhibition | |
2D Materials Focus Topic | Thursday Sessions |
Session 2D-ThP |
Session: | 2D Materials Focus Topic Poster Session |
Presenter: | Michael Shtein, Ben Gurion University, Israel |
Authors: | M. Shtein, Ben Gurion University, Israel O. Regev, Ben Gurion University, Israel |
Correspondent: | Click to Email |
The rapidly increasing device densities in electronics dictate the need for efficient thermal management. If successfully exploited, graphene, which possesses extraordinary thermal properties, can be commercially utilized in polymer composites with ultrahigh thermal conductivity (TC). The total potential of graphene to enhance TC, however, is restricted by the large interfacial thermal resistance between the polymer mediated graphene boundaries. We report a facile and scalable dispersion of commercially available graphene nano platelets (GnPs) in a polymer matrix, which formed composite with an ultra-high TC of 12.4 W/mK (vs. 0.2 W/mK for neat polymer).[1] This ultra-high TC was achieved by applying high compression forces during the dispersion resulting in gap closure between adjacent GnPs with large lateral dimensions and low defect densities. We also found strong evidences for the existence of a thermal percolation threshold. Finally, the addition of electrically insulating nano-boron nitride to the thermally conductive GnP-polymer composite significantly reduces its electrical conductivity (to avoid short circuit) and synergistically increases the TC. The efficient dispersion of commercially available GnPs in polymer matrix provides an ideal framework for substantial progress toward large-scale production and commercialization of GnP-based thermally conductive composites.
Reference: Shtein M., Nadiv R., Buzaglo M., Kahil K. and Regev O., Thermally conductive graphene-polymer composites: size, percolation and synergy effects, Chemistry of Materials, 2015, 27, 2100–2106 .