AVS 62nd International Symposium & Exhibition
    2D Materials Focus Topic Thursday Sessions
       Session 2D+EM+MG+NS+SE+SM+SS+TF-ThM

Paper 2D+EM+MG+NS+SE+SM+SS+TF-ThM10
A Kinetic Study on the Adsorption of Polar (Water) and Non-Polar (Benzene) Molecules on CVD Graphene

Thursday, October 22, 2015, 11:00 am, Room 212C

Session: Emergent 2D Materials
Presenter: Nilushni Sivapragasam, North Dakota State University
Authors: N. Sivapragasam, North Dakota State University
U. Burghaus, North Dakota State University
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The adsorption kinetics of water and benzene at ultrahigh vacuum conditions were studied. Two different chemical vapor deposited graphene samples (graphene/SiO2 and graphene/Cu) were utilized. Different surface analytical techniques (Auger electron spectroscopy, X-ray photoelectron spectroscopy, and Raman spectroscopy) were used to characterize the surface. Subsequently, a kinetics study - to understand the adsorption of water and benzene- using thermal desorption spectroscopy (TDS) was conducted. The TDS results revealed the hydrophobicity of water on graphene. However, the adsorption kinetics of water on graphene did not mimic the bare substrate, i.e., graphene is non-transparent for water adsorption. In contrast, graphene was transparent for benzene adsorption. Furthermore, the adsorption kinetics of both, water and benzene were substrate dependent.