AVS 62nd International Symposium & Exhibition
    2D Materials Focus Topic Friday Sessions
       Session 2D+EM+IS+NS+PS+SP+SS-FrM

Paper 2D+EM+IS+NS+PS+SP+SS-FrM5
Intrinsic Wettability of Graphene

Friday, October 23, 2015, 9:40 am, Room 212C

Session: Surface Chemistry of 2D Materials: Functionalization, Membranes, Sensors
Presenter: Haitao Liu, Department of Chemistry, University of Pittsburgh
Correspondent: Click to Email

Graphene and graphite are long believed to be hydrophobic. Here we show that a clean graphitic surface is in fact mildly hydrophilic [1]. We find that an as-prepared graphene sample is hydrophilic with a water contact angle of ca. 40o. Upon exposure to ambient air, the water contact angle gradually increased to ca. 60o within 20 min and plateaued at ca. 80o after 1 day. Infrared (IR) spectroscopy and X-ray photoelectron spectroscopy (XPS) showed that airborne hydrocarbon adsorbed onto the graphene surface during this process. Both thermal annealing and controlled UV/O3 treatment removed the hydrocarbon contaminants, which was accompanied by a concurrent decrease in the water contact angle. Our findings show that graphene is more hydrophilic than previously believed and suggest that the reported hydrophobic nature of graphene is due to unintentional hydrocarbon contamination from ambient air.

Reference

[1] Zhiting Li; et al.; Nature Materials, 12, 925-931, (2013)