AVS 61st International Symposium & Exhibition
    Novel Trends in Synchrotron and FEL-Based Analysis Focus Topic Tuesday Sessions
       Session SA-TuM

Invited Paper SA-TuM5
Growth and Characterization of Low Dimensional Materials for Applications in Energy and Sensor Devices

Tuesday, November 11, 2014, 9:20 am, Room 312

Session: Characterization of Nanostructured and LD Materials Using Synchrotron-Based Methods
Presenter: Andrea Goldoni, Elettra-Sincrotrone Trieste, Italy
Correspondent: Click to Email

Nanostructured low dimensional systems, in particular carbon nanotubes and oxide nanopillars, have a number of aspects that make them suitable for applications in the fields of environmental gas sensors and energy devices. Here we present the growth and characterization of some nanostructures of interest [1-3] made by well-ordered tin oxide nanopillars on ITO and hybrid/functionalized carbon nanostructures, suitable both as electrodes for solar and electrochemical cells, as well as for extremely fast (and sensitive) gas sensors [4-6].

[1] S. Hofmann et al., "In-situ observations of catalyst dynamics during surface-bound carbon nanotube nucleation", Nano Letters 7, 602 (2007); C. Mattevi et al., “In-situ XPS study of catalyst-support interactions and growth of carbon nanotube forests”, J. Phys. Chem. C 112, 12207 (2008).

[2] L. D’Arsiè et al.,, “Tubular Sn-Filled Carbon Nanostructures on Indium Tin Oxide: Nanocomposite material for multiple applications”, Carbon 65, 13 (2013).

[3] P. Mbuyisa et al., “Controlled Synthesis of Carbon-Based Nanostructures Using Aligned ZnO Nanorods as Templates”, Carbon 50, 5472 (2012).

[4] F.M. Toma et al., “Efficient Water Oxidation at Carbon Nanotube/Polyoxometalate Electrocatalytic Interfaces”, Nature Chemistry 2, 826 (2010); S. Piccinin, et al., "Unifying Concepts in Water Oxidation Catalysis: Thermodynamic and kinetic pathways powered by a molecular, tetraruthenium-oxo complex as the blue-print of metal-oxide surfaces", PNAS 110, 4917 - 4922 (2013).

[5] F. Rigoni et al., “Enhancing the sensitivity of pristine carbon nanotubes to detect low-ppb ammonia concentrations in the environment”, Analyst 138, 7392 (2013); F. Rigoni et al, “Water selective, high sensitivity gas sensors based on single-wall carbon nanotubes functionalized with indium tin oxide nanoparticles: towards low ppb detection of ammonia concentrations in the environment”, submitted (2014).

[6] V. Alijani et al., “Extremely Sensitive and Fast Sensors Made of Vertical Nanostructures of SnOx on Indium Tin Oxide”, submitted (2014).