AVS 61st International Symposium & Exhibition
    In-Situ Spectroscopy and Microscopy Focus Topic Tuesday Sessions
       Session IS+AS+MC+SS-TuM

Invited Paper IS+AS+MC+SS-TuM5
Ambient Pressure XPS Studies of Fuel Cell and Electrolysis Catalysis

Tuesday, November 11, 2014, 9:20 am, Room 313

Session: Ambient Pressure X-ray Photoelectron Spectroscopy (AP-XPS)
Presenter: Hirohito Ogasawara, SLAC National Accelerator Laboratory
Correspondent: Click to Email

Fuel cell and electrochemical reactions were studied by ambient pressure X-ray photoemission spectroscopy at Stanford Synchrotron Radiation Lightsource (SSRL) [1]. We will present our recent studies: platinum catalyst under different operating conditions of oxygen reduction fuel cell reaction, iridium oxide catalyst during the oxygen evolution reaction and molybdenum sulfides catalyst during the hydrogen evolution reaction. Surface changes under these electrochemical reactions, which are keys to understanding activity and durability will be shown [2,3].

[1] Ambient-pressure photoelectron spectroscopy for heterogeneous catalysis and electrochemistry, CatalysisToday 205 (2013) 101.

[2] Direct observation of the oxygenated species during oxygen reduction on a platinum fuel cell cathode, Nature Communications 4 (2014) 2817

[3] In situ observation of surface species on iridium oxide nanoparticles during the oxygen evolution reaction, submitted