AVS 61st International Symposium & Exhibition
    Electronic Materials and Processing Wednesday Sessions
       Session EM+EN+TF-WeA

Paper EM+EN+TF-WeA9
Rate Capability of Silicon Carbon Nanotube Anodes for Lithium Ion Batteries

Wednesday, November 12, 2014, 5:00 pm, Room 311

Session: Thin Films and Materials for Energy Storage
Presenter: Lawrence Barrett, Brigham Young University
Authors: L. Barrett, Brigham Young University
R. Fan, Brigham Young University
R.C. Davis, Brigham Young University
K. Hinton, Brigham Young University
R.R. Vanfleet, Brigham Young University
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Research has shown stable high capacity lithium ion battery anodes can be made from silicon deposited on carbon nanotubes (CNTs). However, rate capability remains a challenge. We have explored two potential limiting factors: diffusion from the top of the forest down and diffusion into the silicon coating. To probe top down diffusion, we compared a uniform CNT forest to a forest with an array 10 um holes spaced 10 um apart to allow channels for faster top down diffusion and found rate capability was unaffected, indicating top down diffusion is not a limiting factor. We also probed diffusion through the silicon coating by changing the thickness and morphology of the coating.