Paper NS+AS+EN+SS-TuA9
Single Atom Alloys as a Strategy for Selective Heterogeneous Hydrogenations

Tuesday, October 29, 2013, 4:40 pm, Room 203 B

Hydrogenation reactions are central to the petrochemical, fine chemical, pharmaceutical, and food industries and are of increasing interest in energy production and storage technologies. Typical heterogeneous catalysts often involve noble metals and alloys based on platinum, palladium, rhodium and ruthenium. While these metals are active at modest temperature and pressure, they are not always completely selective and are expensive. We have demonstrated that single palladium atoms can convert the otherwise catalytically inert surface of an inexpensive metal into an ultraselective catalyst. We used high resolution imaging to characterize the active sites and temperature programmed reaction spectroscopy to probe the chemistry. The mechanism involves facile dissociation of molecular hydrogen at individual palladium atoms followed by spillover onto the copper surface, where ultraselective catalysis occurs by virtue of weak binding. The reaction selectivity is in fact much higher than that measured on palladium alone, illustrating the unique synergy of the system.