AVS 60th International Symposium and Exhibition
    Biomolecules at Aqueous Interfaces Focus Topic Monday Sessions
       Session BA+AI+AS+BI+IS+NL-MoM

Invited Paper BA+AI+AS+BI+IS+NL-MoM8
Sum Frequency Generation (SFG) Vibrational Spectroscopy Studies of Molecules at Solid-Liquid and Solid-Gas Interfaces

Monday, October 28, 2013, 10:40 am, Room 203 A

Session: Biomolecules at Aqueous Interfaces
Presenter: G.A. Somorjai, University of California, Berkeley and Lawrence Berkeley National Laboratory
Authors: G.A. Somorjai, University of California, Berkeley and Lawrence Berkeley National Laboratory
X. Cai, Lawrence Berkeley National Laboratory
Correspondent: Click to Email

Construction of a femtosecond broad-band laser enables us to simultaneously monitor the CH and CO vibrational SFG spectra, thus allowing more actual characterization of reaction intermediates at solid-liquid and solid-gas interfaces. Using a picosecond laser we compare the spectroscopy using these two different laser systems and they will be discussed in some detail. In addition, sum frequency generation vibrational spectroscopy, high-pressure scanning tunneling microscopy and ambient-pressure X-ray photoelectron spectroscopy as well as other synchrotron-based techniques (X-ray adsorption) that enable the investigation of surfaces under reaction conditions on the atomic and molecular level will be reviewed.

We investigate solid-liquid and solid-solid interfaces (buried interfaces) as they adsorb and react with diatomic and organic molecules in dynamic state at various pressures and temperatures.