AVS 58th Annual International Symposium and Exhibition
    Plasma Science and Technology Division Wednesday Sessions
       Session PS+EM-WeA

Invited Paper PS+EM-WeA1
Electric and Optical Characterization of Leakage and Breakdown in Low-k Dielectric Materials

Wednesday, November 2, 2011, 2:00 pm, Room 202

Session: Low-K Materials & Integration
Presenter: Tony Heinz, Columbia University
Authors: J.M. Atkin, Columbia University
R. Laibowitz, Columbia University
T.M. Shaw, IBM T.J. Watson Research Center
T.F. Heinz, Columbia University
Correspondent: Click to Email

Low-k dielectric thin films are finding increased use in integrated circuits for the faster signal speed that they permit. These materials, however, have higher leakage currents and shorter lifetimes than SiO2–based dielectrics. With the continued push to lower values of k, these problems are becoming more acute.

In this paper, we present results of several complementary characterization techniques for determining key physical properties, such as trap densities and barrier heights, that influence leakage and time-dependent dielectric breakdown (TBBD) phenomena. Electrical characterization techniques include impedance spectroscopy and the measurements of transient currents. In addition, we make use of distinctive optical characterization techniques to obtain specific information about the underlying material properties. Internal photoemission (or photocurrent) spectroscopy yields information on interfacial barrier heights from the photon energies required to induce a current. Optical second-harmonic generation (SHG) provides a sensitive, non-contact method for measuring both photo-driven and spontaneous charge transport. From these methods, we show that the increase in current with long time biasing, which is in turn a precursor to electrical breakdown, can be directly correlated with increased trap densities. Conduction models accounting for the early failure mechanism will be discussed. Partial support for this work from the Semiconductor Research Corporation is gratefully acknowledged